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Thermostats and TRV's
Wall thermostats, when fitted, are in series with the CH signal from the time-switch. Some have a built in resistor ("accelerator heater") to reduce the hysteresis, i.e. the "backlash" in temperature between switching on and switching off. When the thermostat is on, the resistor supplies a minute amount of heat, which makes the thermostat think that the room is slightly warmer than it is, and therefore makes it switch off again earlier. The room temperature will thus fluctuate less. Such thermostats require 3 cores and earth: live, switched output and neutral for the resistor. If live and switched output are interchanged, the resistor will be powered constantly and the advantage will be lost. Simpler/older thermostats only need 2 cores and earth, so if you're replacing a thermostat you might want to check the wiring beforehand to see if you can use this feature.

Wireless thermostats are available, which use radio waves to communicate with the rest of the system. These can be convenient if you wouldn't otherwise be able to site the thermostat in a sensible place because of the wiring. Such devices are battery powered, and this will need replacing periodically. One potential advantage of wireless thermostats is that you can move it around the house with you, ensuring the room you're occupying is the one you're using to determine whether heat is needed.

Some room thermostats are available with timers in that allow different target temperatures to be set for different times of the day or week. 6 different temperatures over a 24-hour period is not unusual, so these give a much greater degree of control over the heating system. An 'optimisation' version is usually available. This will predict when the heating needs to be turned on in order to achieve the target temperature. For example, if you program a desired temperature of 21deg for 7am the thermostat might decide it needs to turn the heating on at 6.30am on one day, but at 6am on another (colder) day.

Unfortunately, room thermostats effectively control the whole CH system by monitoring a single point in the house, and so TRVs (Thermostatic Radiator Valves) are an advantage since they control each radiator. Earlier models tend to have the habit of sticking on or off and have given TRVs a bad name. For some valves it is important that they are installed with regard to the direction of water flow. Some valves don't have this restriction. Some angled valves can be fitted with the head vertical or horizontal, so you can always get the correct flow direction through them.

If all radiators have TRVs, some sort of bypass arrangement must be made, to prevent circulation through the boiler ceasing if all valves close down. The bathroom radiator/heated towel rail may not have a TRV (reasoning being that the heat is needed to dry towels even if the room is warm enough), or there may be a separate bypass loop, controlled by a gate valve, and some distance from the boiler so that there is a reasonable volume of water (and hence a reasonable heat sink) circulating. You may also find a 'pressure detecting' valve that will open up as the TRVs close down.

The cylinder thermostat (tank-stat) is an effective device which switches off the HW when the storage cylinder is fully heated. They can only be used on systems which can CH independently from the HW. (On other systems, a thermostatic valve can be fitted, taking note of the bypass arrangements detailed above - in this case the bathroom radiator may be plumbed in to operate all the time.)